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Reply to comment on 'aggregation-induced phosphorescent emission (AIPE) of iridium(III) complexes': origin of the enhanced phosphorescence.

Authors :
Kewei Huang
Huazhou Wu
Mei Shi
Fuyou Li
Tao Yi
Chunhui Huang
Source :
Chemical Communications; 3/14/2009, Issue 10, p1243-1245, 3p
Publication Year :
2009

Abstract

An obvious enhanced phosphorescence emission in the solid state (EPESS) was observed for two iridium(III) complexes with restricted (even fixed) intramolecular rotational motion, which is contrary to the opinion (''restricted intramolecular rotational motion as the origin of EPESS'') of Park et al., and our observation confirmed that the π-π stacking of adjacent pyridyl rings of ppy ligands played a key role in EPESS. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Issue :
10
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
78044174
Full Text :
https://doi.org/10.1039/b816056b