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Copper(I)-Mediated 1,2-Metallate Rearrangements of 1-Metallated Glycals.
- Source :
- Synthesis; 2012, Vol. 2012 Issue 6, p946-952, 7p
- Publication Year :
- 2012
-
Abstract
- 1,2-Metallate rearrangements involving reaction of 1-metallated glycals with organolithium reagents under copper(I) me-diation give alkenylpolyol chains in 45-91% yield (19 examples). The reaction was applied to a formal synthesis of KRN7000 as well as a synthesis of a δ<superscript>5,6</superscript>-ceramide derivative. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00397881
- Volume :
- 2012
- Issue :
- 6
- Database :
- Complementary Index
- Journal :
- Synthesis
- Publication Type :
- Academic Journal
- Accession number :
- 75196156
- Full Text :
- https://doi.org/10.1055/s-0031-1289721