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Carboxylic acid functionalized imidazolium-based ionic liquids: efficient catalysts for cycloaddition of CO and epoxides.
- Source :
- Reaction Kinetics, Mechanisms & Catalysis; Jun2012, Vol. 106 Issue 1, p25-35, 11p
- Publication Year :
- 2012
-
Abstract
- In this study, a series of imidazolium-based ionic liquids (ILs) having carboxylic acid moieties were synthesized and used as new homogeneous catalysts to synthesize cyclic carbonates from CO and epoxides. Even in the absence of any co-catalyst and organic solvent, carboxylic-acid-functionalized ILs showed better catalytic activity in the coupling reaction of CO and styrene oxide for the production of styrene carbonate than did hydroxyl-functionalized ILs and conventional ILs without any functional moieties. A detailed investigation was carried out on a variety of factors that affected the reactivity, such as the alkyl chain length and the molecular composition of IL molecules including the halide ions. The effect of various reaction parameters such as reaction time, temperature, CO pressure and catalyst amount was also investigated in detail. The mechanism underlying the enhanced rate of the cycloaddition reaction in the presence of carboxylic-acid-functionalized ILs was proposed. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 18785190
- Volume :
- 106
- Issue :
- 1
- Database :
- Complementary Index
- Journal :
- Reaction Kinetics, Mechanisms & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 74713894
- Full Text :
- https://doi.org/10.1007/s11144-011-0399-8