Formation of carboxonium salts in the acylation of alkenes by acylium salts and some problems of the mechanism of acylation.

Authors :: Lyubinskaya, O.
Smit, V.
Shashkov, A.
Chertkov, V.
Kanishchev, M.
Kucherov, V.
Source :: Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1978, Vol. 27 Issue 2, p343-351, 9p
Publication Year :: 1978
Abstract: Acylation of alkenes with branching at the allylic carbon provides a preparative route to cyclic carboxonium salts. Such salts can be prepared by protonation of β, γ-unsaturated ketones -the products of acylation of unbranched alkenes. We have examined the mechanism of acylation of acylium salts. [ABSTRACT FROM AUTHOR]

Language :: English
ISSN :: 05685230
Volume :: 27
Issue :: 2
Database :: Complementary Index
Journal :: Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science
Publication Type :: Academic Journal
Accession number :: 72519770
Full Text :: https://doi.org/10.1007/BF00923873

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