The penetrable square-well model: extensive versus non-extensive phases.

The phase diagram of the penetrable square-well fluid is investigated through Monte Carlo simulations of various nature. This model was proposed as the simplest possibility of combining bounded repulsions at short scale and short-range attractions. We prove that the model is thermodynamically stable for sufficiently low values of the penetrability parameter, and in this case the system behaves similarly to the square-well model. For larger penetration, there exists an intermediate region where the system is metastable, with well-defined fluid–fluid and fluid–solid transitions, at finite size, but eventually it becomes unstable in the thermodynamic limit. We characterize the unstable non-extensive phase appearing at high penetrability, where the system collapses into an isolated blob of a few clusters of many overlapping particles each. [ABSTRACT FROM AUTHOR]