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Desymmetrization of Hepta-1,6-dien-4-ol by Prins Reaction and Subsequent Cross-Metathesis: Access to Diospongine A Homologues.
- Source :
- Synthesis; 2011, Vol. 2011 Issue 24, p4037-4044, 8p
- Publication Year :
- 2011
-
Abstract
- A new tetrahydropyran scaffold has been efficiently prepared by Prins reaction between hepta-1,6-dien-4-ol and benzaldehyde. Subsequent functionalizations were further achieved by Mitsunobu reaction and/or by the way of cross-metathesis/Wacker oxidation sequence to deliver diospongin A analogues. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00397881
- Volume :
- 2011
- Issue :
- 24
- Database :
- Complementary Index
- Journal :
- Synthesis
- Publication Type :
- Academic Journal
- Accession number :
- 69598035
- Full Text :
- https://doi.org/10.1055/s-0031-1289588