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5,5-Dimethyl-2-[6-methyl-2-(methylsulfanyl)pyrimidin-4-yloxy]-1,3,2-dioxaphosphorinane-2-thione.

Authors :
Pop, Mihaela
Borodi, Gheorghe
Goubitz, Kees
Peschar, René
Fraanje, Jan
Fenesan, Ioan
Schenk, Henk
Source :
Acta Crystallographica: Section C (Wiley-Blackwell); May2002, Vol. 58 Issue 5, po280-o281, 1p
Publication Year :
2002

Abstract

The title compound, C<subscript>11</subscript>H<subscript>17</subscript>N<subscript>2</subscript>O<subscript>3</subscript>PS<subscript>2</subscript>, is a cyclic thio­phos­phoryl pyrimidine derivative exhibiting insecticidal properties. The crystal structure determination gives evidence for the presence of the thione isomer of the compound. The pyrimidine nucleus is planar and its substituents have small deviations from the least-squares plane. The dioxaphos­phorinane ring adopts a chair conformation. The lack of classical hydrogen bonds and the weak intermolecular interactions lead to a `loose' packing characterized by channels in the structure. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
01082701
Volume :
58
Issue :
5
Database :
Complementary Index
Journal :
Acta Crystallographica: Section C (Wiley-Blackwell)
Publication Type :
Academic Journal
Accession number :
63601888
Full Text :
https://doi.org/10.1107/S0108270102005218