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cis-Di­bromo- trans-di­methyl- cis-bis( N, N-di­methyl­acet­amide)­tin(IV).

Authors :
König, Uwe-Christoph
Berkei, Michael
Hirsch, Claudia
Preut, Hans
Mitchell, Terence Nigel
Source :
Acta Crystallographica: Section C (Wiley-Blackwell); Oct2000, Vol. 56 Issue 10, pe452-e453, 1p
Publication Year :
2000

Abstract

The synthesis and X-ray structure analysis of the title compound, [SnBr<subscript>2</subscript>(CH<subscript>3</subscript>)<subscript>2</subscript>(C<subscript>4</subscript>H<subscript>9</subscript>NO)<subscript>2</subscript>], are described. The crystal contains mol­ecules which are separated by normal van der Waals distances. Organotin(IV) compounds are found in a variety of structural types, in which the Sn atom can, for example, be hexacoordinated. In this case, the preferred solid-state molecular structure of the central atom is octahedral. The degree of distortion and the configuration depend on the ligands. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
01082701
Volume :
56
Issue :
10
Database :
Complementary Index
Journal :
Acta Crystallographica: Section C (Wiley-Blackwell)
Publication Type :
Academic Journal
Accession number :
63601421
Full Text :
https://doi.org/10.1107/S010827010001221X