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catena-Poly[[dicyanamido(1,10-phenanthroline)copper(II)]-μ-dicyanamido].
- Source :
- Acta Crystallographica: Section C (Wiley-Blackwell); Jul2000, Vol. 56 Issue 7, p786-788, 3p
- Publication Year :
- 2000
-
Abstract
- The title compound, [Cu(C<subscript>2</subscript>N<subscript>3</subscript>)<subscript>2</subscript>(C<subscript>12</subscript>H<subscript>8</subscript>N<subscript>2</subscript>)]<subscript> n</subscript>, has a sheet-like structure, built by [Cu(phen)(dca)<subscript>2</subscript>]<subscript> n</subscript> (phen is 1,10-phenanthroline and dca is dicyan­amide) chains which are interconnected by secondary long Cu-N bonds between the chains. The Cu<superscript>2+</superscript> ion is in a distorted tetragonal bipyramidal (5 + 1) coordination environment. The sheets stack into the three-dimensional crystal structure through aromatic interactions between the coordinated phen ligands of adjacent sheets. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01082701
- Volume :
- 56
- Issue :
- 7
- Database :
- Complementary Index
- Journal :
- Acta Crystallographica: Section C (Wiley-Blackwell)
- Publication Type :
- Academic Journal
- Accession number :
- 63601164
- Full Text :
- https://doi.org/10.1107/S0108270100004984