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Synthesis, structure, and NMR spectra of a new ferrocenylbenzene tricarbonylchromium complex.
- Source :
- Journal of Coordination Chemistry; Jul2011, Vol. 64 Issue 13, p2361-2366, 6p
- Publication Year :
- 2011
-
Abstract
- Complex 1 (1,2,4-triferrocenylbenzene tricarbonylchromium), possessing four heterometals, has been synthesized efficiently by a new method in one pot. Through detailed study on the NMR chemical shifts of 1 and the ligand 2, the NMR chemical shifts of 1 shift upfield from those of 2. The NMR spectra of 1 have reduced magnetic anisotropy of benzene after Cr(CO)3 coordination with 2. The ferrocenyl groups have electron donating effect on the central benzene ring of 1. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 64
- Issue :
- 13
- Database :
- Complementary Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 62597627
- Full Text :
- https://doi.org/10.1080/00958972.2011.599028