Guest-induced gate-opening of a zeolite imidazolate frameworkElectronic supplementary information (ESI) available: Complete series of XRPD. Modeling parameters. See DOI: 10.1039/c0nj00836b.

Authors :: Aguado, Sonia
Bergeret, Gérard
Titus, Marc Pera
Moizan, Virginie
Nieto-Draghi, Carlos
Bats, Nicolas
Farrusseng, David
Source :: New Journal of Chemistry; Mar2011, Vol. 35 Issue 3, p546-550, 5p
Publication Year :: 2011
Abstract: The zinc benzimidazolate coordination polymer (ZIF-7) shows a reversible gate-opening effect upon variation of partial pressure of CO2or temperature. This phenomenon, which is unique for a MOF with sodalite topology, arises from a phase-to-phase transformation upon guest adsorption–desorption. [ABSTRACT FROM AUTHOR]

Subjects :: COORDINATION polymers
ZEOLITES
ADSORPTION (Chemistry)
X-ray diffraction
TOPOLOGY
TEMPERATURE effect

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