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Activation of a water molecule under mild conditions by ruthenacyclopentatriene: mechanism of hydrative cyclization of diynesElectronic supplementary information (ESI) available: Experimental procedures, spectroscopic data, and CIF file. CCDC 766961. For ESI and crystallographic data in CIF or other electronic format see DOI:10.1039/c0cc04345a
- Source :
- Chemical Communications; Feb2011, Vol. 47 Issue 5, p1556-1558, 3p
- Publication Year :
- 2011
-
Abstract
- A ruthenium cyclic biscarbene complex reacted with a H2O molecule under mild conditions to produce η5-oxapentadienyl complex, that proved to be the intermediate in the catalytic hydrative cyclization of a diyne. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 47
- Issue :
- 5
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 57544095
- Full Text :
- https://doi.org/10.1039/c0cc04345a