Optical constants of Cu2ZnGeS4 bulk crystals.

The dielectric functions of Cu₂ZnGeS₄ bulk crystals grown by the Bridgman method were measured over the energy range 1.4 to 4.7 eV at room temperature using variable angle spectroscopic ellipsometry. The observed structures in the dielectric functions were adjusted using the Adachi's model and attributed to interband transitions E₀, E_1A, and E_1B at Γ:(000), N(A):2π/a(0.5 0.5 0.5), and T(Z):2π/a(0 0 0.5) points of the first Brillouin zone, respectively. The model parameters (threshold energy, strength, and broadening) have been determined using the simulated annealing algorithm. The decrease in the first gap, E₀, has been attributed to a higher Ge-S hybridization. The spectral dependence of the complex refractive index, the absorption coefficient, and the normal-incidence reflectivity were also derived. [ABSTRACT FROM AUTHOR]