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The single particle dynamics of iodine in the Sachs-Teller regime: An inelastic x-ray scattering study.

Authors :
Izzo, M. G.
Bencivenga, F.
Cunsolo, A.
Di Fonzo, S.
Verbeni, R.
De Lorenzo, R. Gimenez
Source :
Journal of Chemical Physics; 9/28/2010, Vol. 133 Issue 12, p124514, 5p
Publication Year :
2010

Abstract

The high frequency dynamics of liquid iodine has been investigated by deep inelastic x-ray scattering at exchanged wave-vectors (q) ranging from 2.5 to 15 Å<superscript>-1</superscript>. The experimental data have been analyzed in the frame of the Sachs-Teller theory of the molecular spectrum while accounting for final state corrections to the lineshape. The performed data analysis carries insights on physical quantities as relevant as the mean rototranslational kinetic energy and the mean square Laplacian of the intermolecular potential. In both cases the measured values are consistent with corresponding theoretical expectations. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
133
Issue :
12
Database :
Complementary Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
54050020
Full Text :
https://doi.org/10.1063/1.3483689