Back to Search Start Over

Reaction of mercury salts with dimethyl tricyclo [4.2.2.02,5]deca-3,7-diene- cis- endo-9,10-dicarboxylate in acetic acid.

Reaction of mercury salts with dimethyl tricyclo [4.2.2.02,5]deca-3,7-diene- cis- endo-9,10-dicarboxylate in acetic acid.

Authors :
Kartashov, V.
Sokolova, T.
Salikova, T.
Grishin, Yu.
Zefirov, N.
Source :
Russian Chemical Bulletin; Nov1999, Vol. 48 Issue 11, p2149-2152, 4p
Publication Year :
1999

Abstract

The reaction of dimethyl tricyclo[4.2.2.0<superscript>2,5</superscript>]deca-3,7-diene- cis- endo-9,10-dicarboxylate with mercury salts Hg(OCOR)<subscript>2</subscript> (R=CCl<subscript>3</subscript>, CF<subscript>3</subscript>, CH<subscript>2</subscript>Cl) in acetic acid yields a mixture of solvoadducts and products of addition of the anionic moiety of the reagent having the trans-configuration. In the case of Hg(OCOCCl<subscript>3</subscript>)<subscript>2</subscript>, cis-solvoadduct was detected along with the trans-isomer. The amount of the addition products is determined by the nature of the mercury salt and increases in the order Hg(OCOCH<subscript>2</subscript>Cl)<subscript>2</subscript><Hg(OCOCCl<subscript>3</subscript>)<subscript>2</subscript>=Hg(OCOCF<subscript>3</subscript>)<subscript>2</subscript>. The reaction is assumed to involve contact and solvent-separated ion pairs. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
10665285
Volume :
48
Issue :
11
Database :
Complementary Index
Journal :
Russian Chemical Bulletin
Publication Type :
Academic Journal
Accession number :
52188882
Full Text :
https://doi.org/10.1007/BF02494865