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A new Cu(i) coordination polymer with the CdSO4structure type prepared viabiphasic solvothermal reactionElectronic supplementary information (ESI) available: Crystal data and TGA for BPS-1. CCDC reference number 738444. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b919342c
A new Cu(i) coordination polymer with the CdSO4structure type prepared viabiphasic solvothermal reactionElectronic supplementary information (ESI) available: Crystal data and TGA for BPS-1. CCDC reference number 738444. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b919342c
- Source :
- CrystEngComm; Jul2010, Vol. 12 Issue 7, p2018-2020, 3p
- Publication Year :
- 2010
-
Abstract
- Biphasic solvothermal reaction of Cu(NO3)2·6H2O and 2,3,5,6-tetramethyl-1,4-benzenedicarboxylic acid (H2TBDC) resulted in the formation of a novel coordination polymer, [Cu(TBDC)1/2]·H2O (BPS-1). BPS-1possesses a 3D framework containing 1D Cu(i)–COO helical chains. The use of an organic solvent with a high boiling point and an extension of the reaction time play important roles in the reduction of Cu(ii) ions to Cu(i) ions and the formation of BPS-1. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 12
- Issue :
- 7
- Database :
- Complementary Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 51995112
- Full Text :
- https://doi.org/10.1039/b919342c