Back to Search Start Over

A new Cu(i) coordination polymer with the CdSO4structure type prepared viabiphasic solvothermal reactionElectronic supplementary information (ESI) available: Crystal data and TGA for BPS-1. CCDC reference number 738444. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b919342c

A new Cu(i) coordination polymer with the CdSO4structure type prepared viabiphasic solvothermal reactionElectronic supplementary information (ESI) available: Crystal data and TGA for BPS-1. CCDC reference number 738444. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b919342c

Authors :
Tuoping Hu
Haiyan He
Fangna Dai
Xiaoliang Zhao
Daofeng Sun
Source :
CrystEngComm; Jul2010, Vol. 12 Issue 7, p2018-2020, 3p
Publication Year :
2010

Abstract

Biphasic solvothermal reaction of Cu(NO3)2·6H2O and 2,3,5,6-tetramethyl-1,4-benzenedicarboxylic acid (H2TBDC) resulted in the formation of a novel coordination polymer, [Cu(TBDC)1/2]·H2O (BPS-1). BPS-1possesses a 3D framework containing 1D Cu(i)–COO helical chains. The use of an organic solvent with a high boiling point and an extension of the reaction time play important roles in the reduction of Cu(ii) ions to Cu(i) ions and the formation of BPS-1. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14668033
Volume :
12
Issue :
7
Database :
Complementary Index
Journal :
CrystEngComm
Publication Type :
Academic Journal
Accession number :
51995112
Full Text :
https://doi.org/10.1039/b919342c