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Molecular structure and electrochemistry of carbon-bridged diferrocenyl compounds.
- Source :
- Journal of Coordination Chemistry; May2010, Vol. 63 Issue 10, p1700-1710, 11p, 7 Diagrams, 3 Charts, 1 Graph
- Publication Year :
- 2010
-
Abstract
- Four diferrocenyl compounds: FcC(CH3)2Fc (1), Fc(CH3)C(C2H5)Fc (2), Fc(CH3)C(C3H7)Fc (3), and Fc(CH3)C(C6H5)Fc (4) were synthesized and characterized by NMR, FT-IR, MS, and elemental analysis. The molecular structures were determined by using X-ray single crystal diffraction. The electrochemical interactions between two ferrocenyl units in these compounds were investigated by cyclic voltammetry and theoretical calculation. The electron density of bridging carbon was a key factor for the separation of two ferrocenyl units. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 63
- Issue :
- 10
- Database :
- Complementary Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 51376640
- Full Text :
- https://doi.org/10.1080/00958972.2010.487102