New technology for selective catalytic oxidation of ammonia to nitrogen.

The selective catalytic oxidation (SCO) of ammonia to N₂ was studied by using a series of noble metal-V₂O₅-WO₃ catalysts supported on titania-silica (TS) prepared by coprecipitation method. In the V₂O₅-WO₃ catalyst system, the use of TS as a support was very effective to enhance catalytic activity compared with TiO₂ or SiO₂ alone. The addition of a slight amount of Pd and Ir to V₂O₅-WO₃/TS catalyst caused also remarkable enhancement of the catalytic activity without decreasing the selectivity to N₂. The present catalysts provide remarkably high catalytic performance for SCO of ammonia to N₂ under the practical reaction conditions for an industrial application. [ABSTRACT FROM AUTHOR]