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Trapping in situscission products of C–O ester bonds by unique coordination supramolecular architecturesElectronic supplementary information (ESI) available: Syntheses of 1,2-BAB, 1,3-BAB, 1, 2, 3 and 4; IR spectra, Figures and crystal data of complexes 1, 2, 3and 4. CCDC reference numbers 711394–711397. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b904387j
- Source :
- CrystEngComm; Sep2009, Vol. 11 Issue 9, p1815-1818, 4p
- Publication Year :
- 2009
-
Abstract
- Various decomposition products of C–O ether bond cleavage have been trapped in supramolecular architectures as templates based on hydrothermal reaction of three-component metal–carboxylate–phen, which not only results in the formation of [5]pseudorotaxane structure, 3D porous framework and supramolecular structure, but also provides directly crystallographic evidence to explain how the C–O ether bond breaks during decomposition. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 11
- Issue :
- 9
- Database :
- Complementary Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 44045187
- Full Text :
- https://doi.org/10.1039/b904387j