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Substituted Esters of Coumarin-3-phosphonic Acid—Linear-Polarized IR-Spectroscopic Elucidation.
- Source :
- Phosphorus, Sulfur & Silicon & the Related Elements; Dec2008, Vol. 183 Issue 12, p2998-3012, 15p, 3 Diagrams, 1 Chart, 8 Graphs
- Publication Year :
- 2008
-
Abstract
- Correlation between the structure and IR-spectroscopic properties of two halogen and one amino substituted esters of coumarin-3-phosphonic acid has been studied by means of linear-polarized IR-spectroscopy of oriented colloid suspensions in nematic host. The influence of the ester group on the peak positions of the IR-characteristic bands of these derivatives and in particular, on phosphorus group is investigated by a comparison with the data for corresponding coumarin-3-phosphonic acids. Theoretical quantum chemical DFT calculations (B3LYP/6-311++G**) are carried out, thus supporting the experimental assignment of the IR-bands and predicting the electronic structure of all of the compounds studied. [ABSTRACT FROM AUTHOR]
- Subjects :
- ESTERS
COUMARINS
BENZOPYRANS
PHOSPHONATES
ORGANIC compounds
Subjects
Details
- Language :
- English
- ISSN :
- 10426507
- Volume :
- 183
- Issue :
- 12
- Database :
- Complementary Index
- Journal :
- Phosphorus, Sulfur & Silicon & the Related Elements
- Publication Type :
- Academic Journal
- Accession number :
- 35034825
- Full Text :
- https://doi.org/10.1080/10426500802049837