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Protein scaffold of a designed metalloenzyme enhances the chemoselectivity in sulfoxidation of thioanisole.
- Source :
- Chemical Communications; Mar2008, Vol. 2008 Issue 14, p1665-1667, 3p
- Publication Year :
- 2008
-
Abstract
- We demonstrate that incorporation of MnSalen into a protein scaffold enhances the chemoselectivity in sulfoxidation of thioanisole and find that both the polarity and hydrogen bonding of the protein scaffold play an important role in tuning the chemoselectivity. [ABSTRACT FROM AUTHOR]
- Subjects :
- PROTEIN synthesis
HYDROGEN bonding
METALLOENZYMES
SCIENTIFIC experimentation
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 2008
- Issue :
- 14
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 32120302
- Full Text :
- https://doi.org/10.1039/b718915j