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Laser ablation of a platinum target in water. III. Laser-induced reactions.
- Source :
- Journal of Applied Physics; 12/1/2006, Vol. 100 Issue 11, p114913, 7p, 2 Diagrams, 1 Chart, 3 Graphs
- Publication Year :
- 2006
-
Abstract
- This is the third paper in our series studying the laser-target-liquid interactions occurring in laser ablation in liquids (LAL). Here, laser ablation of a platinum target in pure water at 355 nm wavelength is studied as a function of laser energy. We describe three distinct reaction regimes between the ablated target species and water at different laser focusing conditions. At low laser fluence (<10 J/cm<superscript>2</superscript>), material removal is caused by laser heating of the platinum surface and the primary products are small clusters with a large percentage of platinum atoms in a nonzero oxidation state. At intermediate fluences (10–70 J/cm<superscript>2</superscript>), platinum nanoparticles are the primary products. Our previous studies demonstrated that in this fluence regime ablation occurs through both thermal vaporization and explosive ejection of molten droplets. In both cases reactivity is small due to the low reactivity of platinum with water. At high fluences (>70 J/cm<superscript>2</superscript>), we find large, faceted particles that are attributed to the drying of PtO<subscript>x</subscript> gels formed by reactive plasma etching of the target. Taken together these results demonstrate that significant tunability in the target-liquid interaction is possible during nanomaterial synthesis by LAL. [ABSTRACT FROM AUTHOR]
- Subjects :
- LASER ablation
INDUSTRIAL lasers
PLATINUM
NANOPARTICLES
PLASMA etching
Subjects
Details
- Language :
- English
- ISSN :
- 00218979
- Volume :
- 100
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Journal of Applied Physics
- Publication Type :
- Academic Journal
- Accession number :
- 30106461
- Full Text :
- https://doi.org/10.1063/1.2390642