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catena-Poly[[[tetraaquazinc(II)]-μ-4,4′-bipyridine] bis(4-hydroxybenzenesulfonate) trihydrate].
- Source :
- Acta Crystallographica: Section C (Wiley-Blackwell); Nov2006, Vol. 62 Issue 11, pm522-m524, 3p, 7 Diagrams, 2 Charts
- Publication Year :
- 2006
-
Abstract
- In the title compound, {[Zn(C<subscript>10</subscript>H<subscript>8</subscript>N<subscript>2</subscript>)(H<subscript>2</subscript>O)<subscript>4</subscript>](C<subscript>6</subscript>H<subscript>5</subscript>O<subscript>4</subscript>S)<subscript>2</subscript>·3H<subscript>2</subscript>O}<subscript> n</subscript>, the Zn atom, the bipyridine ligand and one of water mol­ecules are located on twofold rotation axes. The Zn atom is coordinated by four O atoms from four water mol­ecules and two N atoms from two 4,4′-bipyridine mol­ecules in a distorted octa­hedral geometry. The Zn<superscript>2+</superscript> ions are linked by the 4,4′-bipyridine mol­ecules to form a one-dimensional straight chain propagating along the c axis. The 4-hydroxy­benzene­sulfonate counter-ions are bridged by the solvent water mol­ecules through hydrogen bonds to generate a two-dimensional layer featuring large pores. In the crystal packing, the intra­layer pores form one-dimensional channels along the c axis, in which the one-dimensional [Zn(C<subscript>10</subscript>H<subscript>8</subscript>N<subscript>2</subscript>)(H<subscript>2</subscript>O)<subscript>4</subscript>]<superscript>2+</superscript> chains are encapsulated. Electrostatic inter­actions between cations and anions and extensive hydrogen bonds result in a three-dimensional supra­molecular structure. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01082701
- Volume :
- 62
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Acta Crystallographica: Section C (Wiley-Blackwell)
- Publication Type :
- Academic Journal
- Accession number :
- 23065275
- Full Text :
- https://doi.org/10.1107/S0108270106038844