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cis-Bis[(3-aminopropyl)dimethylphosphine-κ2 N, P]palladium(II) dichloride methanol solvate.
- Source :
- Acta Crystallographica: Section C (Wiley-Blackwell); Oct2006, Vol. 62 Issue 10, pm461-m463, 1p, 2 Diagrams, 2 Charts
- Publication Year :
- 2006
-
Abstract
- In the title compound, cis-[Pd(C<subscript>5</subscript>H<subscript>14</subscript>NP)<subscript>2</subscript>]Cl<subscript>2</subscript>·CH<subscript>4</subscript>O, the coordination geometry around the Pd<superscript>II</superscript> center is distorted square planar, with a cis-P<subscript>2</subscript>N<subscript>2</subscript> configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (C<subscript>s</subscript>)-chair<subscript>2</subscript> conformer. The distances between the Pd<superscript>II</superscript> center and the Cl<superscript>-</superscript> anions are greater than 4.5 Å, indicating no obvious interaction. [ABSTRACT FROM AUTHOR]
- Subjects :
- METHANOL
AMINO compounds
CATIONS
GEOMETRY
ANIONS
LIGANDS (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 01082701
- Volume :
- 62
- Issue :
- 10
- Database :
- Complementary Index
- Journal :
- Acta Crystallographica: Section C (Wiley-Blackwell)
- Publication Type :
- Academic Journal
- Accession number :
- 22554670
- Full Text :
- https://doi.org/10.1107/S0108270106023596