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The Synthesis and Characterization of 2-Amino-3-methylpyridinium Dihydrogenmonophosphate: (C 6 H 9 N 2 )H 2 PO 4.
- Source :
- Phosphorus, Sulfur & Silicon & the Related Elements; Sep2006, Vol. 181 Issue 9, p2117-2133, 16p, 4 Diagrams, 5 Charts, 10 Graphs
- Publication Year :
- 2006
-
Abstract
- A new crystal of 2-amino-3-methylpyridinium dihydrogenmonophosphate has been prepared and characterized by X-ray crystallography, thermal analysis, and impedance and NMR spectroscopies. This compound crystallizes in the triclinic space group P with a = 7.343(2) Å, b = 7.987(2) Å, c = 8.116(4) Å, α = 77,62(3)°, β = 77,74(3)°, γ = 87,03(2)°, V = 454.3 (3)Å 3 , and Z = 2. The crystal structure was solved and refined to R = 0.030 with 1602 independent reflections. The atomic arrangement can be described as (H 2 PO 4 - ) n polymeric chains anchoring the 2-amino-3-methylpyridinium cations through short hydrogen bonds. All ring atoms of the organic entity are coplanar. The exocyclic N atom is an electron receiving center, which is consistent with features of imino resonance evidenced by bond lengths and angles. Solid state 31 P, 13 C, and 15 N CP-MAS-NMR spectroscopies are in agreement with the X-ray structure. Ab initio calculations allow the attribution of carbons and nitrogen to the independent crystallographic sites. [ABSTRACT FROM AUTHOR]
- Subjects :
- CRYSTALS
CRYSTALLOGRAPHY
THERMAL analysis
HYDROGEN bonding
ATOMS
Subjects
Details
- Language :
- English
- ISSN :
- 10426507
- Volume :
- 181
- Issue :
- 9
- Database :
- Complementary Index
- Journal :
- Phosphorus, Sulfur & Silicon & the Related Elements
- Publication Type :
- Academic Journal
- Accession number :
- 21808241
- Full Text :
- https://doi.org/10.1080/10426500600614196