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Unexpected Addition of Methyl 3,3,3-Trifluoropyruvate to Push-Pull Enamines Having a Methyl Group at α-Position.
- Source :
- Synthesis; 10/18/2004, Vol. 2004 Issue 15, p2545-2549, 5p
- Publication Year :
- 2004
-
Abstract
- The reaction of push-pull enamines having a methyl group at the α-position with methyl 3,3,3-trifluoropyruvate was investigated. As a result, unexpected addition of pyruvate to methyl group was found and a set of polyfunctionalized β-dicarbonyl compounds was obtained. Possible mechanism of the reaction is discussed. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00397881
- Volume :
- 2004
- Issue :
- 15
- Database :
- Complementary Index
- Journal :
- Synthesis
- Publication Type :
- Academic Journal
- Accession number :
- 20153323
- Full Text :
- https://doi.org/10.1055/s-2004-831216