Urban ozone formation and sensitivities to volatile chemical products, cooking emissions, and NO x upwind of and within two Los Angeles Basin cities.

Volatile chemical products (VCPs) and other non-traditional anthropogenic sources, such as cooking, contribute substantially to the volatile organic compound (VOC) budget in urban areas, but their impact on ozone formation is less certain. This study employs Lagrangian box modeling and sensitivity analyses to evaluate ozone response to sector-specific VOC and nitrogen oxide (NO_x) emissions in two Los Angeles (LA) Basin cities during the summer of 2021. The model simulated the photochemical processing and transport of temporally and spatially gridded emissions from the FIVE-VCP-NEI17NRT inventory and accurately simulates the variability and magnitude of O₃, NO_x, and speciated VOCs in Pasadena, CA. VOC sensitivity analyses show that anthropogenic VOCs (AVOC) enhance the mean daily maximum 8 h average ozone in Pasadena by 13 ppb, whereas biogenic VOCs (BVOCs) contribute 9.4 ppb. Of the ozone influenced by AVOCs, VCPs represent the largest fraction at 45 %, while cooking and fossil fuel VOCs are comparable at 26 % and 29 %, respectively. NO_x sensitivity analyses along trajectory paths indicate that the photochemical regime of ozone varies spatially and temporally. The modeled ozone response is primarily NO_x-saturated across the dense urban core and during peak ozone production in Pasadena. Lowering the inventory emissions of NO_x by 25 % moves Pasadena to NO_x-limited chemistry during afternoon hours and shrinks the spatial extent of NO_x saturation towards downtown LA. Further sensitivity analyses show that using VOCs represented by a separate state inventory requires steeper NO_x reductions to transition to NO_x sensitivity, further suggesting that accurately representing VOC reactivity in inventories is critical to determining the effectiveness of future NO_x reduction policies. [ABSTRACT FROM AUTHOR]