The differences between remote sensing and in situ air pollutant measurements over the Canadian oil sands.

Ground-based remote sensing instruments have been widely used for atmospheric research, but applications for air quality monitoring remain limited. Compared to an in situ instrument that provides air quality conditions at the ground level, most remote sensing instruments (nadir viewing) are sensitive to a broad range of altitudes, often providing only integrated column observations. These column data can be more difficult to interpret and to relate to surface values and hence to "nose-height-level" health factors. This research utilized ground-based remote sensing and in situ air quality observations in Canada's Athabasca oil sands region to investigate some of their differences. Vertical column densities (VCDs) of SO₂ and NO₂ retrieved by Pandora spectrometers located at the Oski-Otin site at Fort McKay (Alberta, Canada) from 2013–2019 were analyzed along with measurements of SO₂ and NO₂ surface concentrations and meteorological data. Aerosol optical depth (AOD) observations by a CIMEL sunphotometer were compared with surface PM_2.5 data. The Oski-Otin site is surrounded by several large bitumen mining operations within the Athabasca oil sands region with significant NO₂ emissions from the mining fleet. Two major bitumen upgraders that are 20 km south-east of the site have total SO₂ and NO₂ emissions of about 40 and 20 kt yr⁻¹, respectively. It was demonstrated that remote sensing data from Pandora and CIMEL combined with high-vertical-resolution wind profiles can provide information about pollution sources and plume characteristics. Elevated SO₂ VCDs were clearly observed for times with south and south-eastern winds, particularly at 200–300 m altitude (above ground level). High NO₂ VCD values were observed from other directions (e.g., north-west) with less prominent impacts from 200–300 m winds. In situ ground observations of SO₂ and NO₂ show a different sensitivity to wind profiles, indicating they are less sensitive to elevated plumes than remote sensing instruments. In addition to measured wind data and lidar-observed boundary layer height (BLH), modelled wind profiles and BLH from ECMWF Reanalysis v5 (ERA5) have been used to further examine the correlation between column and surface observations. The results show that the height of emission sources (e.g., emissions from high stacks or near the surface) will determine the ratio of measured column and surface concentration values (i.e., could show positive or negative correlation with BLH). This effect will have an impact on the comparison between column observations (e.g., from the satellite or ground-based remote sensing instruments) with surface in situ measurements. This study explores differences between remote sensing and in situ instruments in terms of their vertical, horizontal, and temporal sampling differences. Understanding and resolving these differences are critical for future analyses linking satellite, ground-based remote sensing and in situ observations in air quality monitoring and research. [ABSTRACT FROM AUTHOR]