Chiral-driven formation of hybrid cyanurates with large birefringence.

Ultraviolet (UV) birefringent crystals have important applications in polarizers, optical isolators and optical information processing. Crystals with large birefringence can enhance the modulation ability of light and realize the miniaturization of devices. However, the birefringence of cyanurates is often limited by the large dihedral angles between anionic groups. In this work, a chiral-driven approach is proposed for the first time to construct cyanurates with large birefringence. We combined racemic or chiral α-methylbenzylamine (α-MBA) molecules with a π-conjugated cyanurate group (CY), which led to the isolation of three organic hybrid cyanurates with wide band gaps >5.10 eV, namely, rac-α-MBACY, R-α-MBACY, and S-α-MBACY. Notably, the presence of chirality leads to a significant reduction of the dihedral angle between the α-MBA cation and (H₂C₃N₃O₃)⁻ anion and a threefold increase in birefringence from 0.113@546 nm to 0.344@546 nm and 0.338@546 nm. The birefringence values of R-α-MBACY and S-α-MBACY exceed those of most of the cyanurates and commercial crystals, indicating their potential as UV birefringent crystals. This work provides new insights into the design and syntheses of UV birefringent materials. [ABSTRACT FROM AUTHOR]