Color‐Tunable White Circularly Polarized Electroluminescence Triggered Using Chiral Co‐Assembly‐Sensitized Strategy.

White circularly polarized organic light‐emitting diodes (CP‐WOLEDs) are central to prospective 3D displays and lighting sources. However, owing to the unwanted charge trapping effect and inefficient chirality transfer, the development of CP‐WOLEDs with a high color rendering index (CRI) and large dissymmetry factor (gEL) is challenging. Herein, a pioneering strategy of chiral co‐assembly‐sensitized circularly polarized luminescence (CCS‐CPL) is proposed for improving the performance of white circularly polarized electroluminescence (CP‐EL). Chiral co‐assembled sensitizers ((S‐/R‐Cz)0.2‐(I‐P)0.8) are smartly developed using π–π stacking interactions between the chiral binaphthyl derivatives (S‐/R‐Cz) and achiral conjugated pyrene‐based polymer (I‐P) in a molar ratio of 1:4. Using the chiral co‐assembly‐sensitized strategy on achiral aggregation‐induced emission (AIE) dyes for emitting layers (EMLs) of OLEDs, full‐color achiral AIE‐active dyes can be sensitized by chiral co‐assembly (S‐/R‐Cz)0.2‐(I‐P)0.8. The color‐tunable white CP‐EL performance can be achieved at the CIE coordinates of (0.33, 0.33) with an ultrahigh CRI of 93 and a large gEL value up to 0.071. This study thus provides a valuable guidance for CCS‐type CP‐WOLEDs. [ABSTRACT FROM AUTHOR]