Statistical Study of the Characteristics of Coal Spontaneous Combustion Gases and Temperature.

The occurrence of coal spontaneous combustion has a significant impact on both the safety of personnel and mine recovery. In order to establish an early warning system for combustion, it is crucial to develop a mathematical model that characterizes indicator gases and coal temperature. In this study, we investigated the O₂, CO, and CO₂ characteristics of data collected from a goaf beam pipe in the Mengcun mine. Our findings demonstrate a linear decrease in O₂ concentration with goaf depth and a strong negative correlation between CO and O₂. We observed that CO/∆O₂ and CO/CO₂ increased to a maximum and then decreased as the goaf depth increased. Furthermore, we found that the peaks of these parameters at the same sampling point corresponded to the same goaf depth, and both occurred at the junction between the air-leakage and oxidation zones. By using a logistic model to fit the CO and C₂H₄ data, we developed a model that characterizes the relationships among CO, C₂H₄, and coal temperature based on statistical laws. The model provides direct information about the inflection point temperatures of C₂H₄ and CO, with the former being slightly lower within the same coal sample. The overall difference between the inflection point temperatures is relatively small, about 10°C. The initial temperature ratio of C₂H₄ and CO remains essentially constant at 3.8. C₂H₂ concentrations are low and irregular, and the presence of this gas can be used to assess when coal enters the accelerated oxidation stage. This research result provides a new research view for elucidating the distribution characteristics of coal spontaneous combustion index gas. [ABSTRACT FROM AUTHOR]