The Difunctionalization of Alkenes Completed by DMTSM and CF3 SO2 Na without Metal Catalysts.

The electrophilic thiolation of alkenes initiated by DMTSM and the addition of CF₃ SO₂ Na in one pot has been developed. This reaction also can be extended to ArSO₂ Na. This protocol features a good substrate scope, simple procedures, and mild reaction conditions and affords the desired products in moderate yields without metal catalysts. [ABSTRACT FROM AUTHOR]