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Innentitelbild: Dearomative Construction of 2D/3D Frameworks from Quinolines via Nucleophilic Addition/Borateā€Mediated Photocycloaddition (Angew. Chem. 41/2024).

Authors :
Shimose, Asuha
Ishigaki, Shiho
Sato, Yu
Nogami, Juntaro
Toriumi, Naoyuki
Uchiyama, Masanobu
Tanaka, Ken
Nagashima, Yuki
Source :
Angewandte Chemie; 10/7/2024, Vol. 136 Issue 41, p1-1, 1p
Publication Year :
2024

Abstract

The article titled "Innentitelbild: Dearomative Construction of 2D/3D Frameworks from Quinolines via Nucleophilic Addition/Borate-Mediated Photocycloaddition" discusses the construction of 2D/3D frameworks from 2D aromatics, specifically quinolines. The cover image illustrates the transformation of quinolines into triply-fused 2D/3D rings through nucleophilic addition, borate complex formation, and photocycloaddition. Mechanistic studies revealed that the borate complex accelerates the photocycloaddition process and suppresses rearomatization in the excited state. The research was conducted by Ken Tanaka, Yuki Nagashima, and their team. [Extracted from the article]

Details

Language :
English
ISSN :
00448249
Volume :
136
Issue :
41
Database :
Complementary Index
Journal :
Angewandte Chemie
Publication Type :
Academic Journal
Accession number :
180043673
Full Text :
https://doi.org/10.1002/ange.202414124