Oxidation Behavior of Lightweight Al 0.2 CrNbTiV High Entropy Alloy Coating Deposited by High-Speed Laser Cladding.

High-temperature oxidation resistance is the major influence on the high-temperature service stability of refractory high entropy alloys. The oxidation behavior of lightweight Al_0.2CrNbTiV refractory high entropy alloy coatings with different dilution ratios at 650 °C and 800 °C deposited by high-speed laser cladding was analyzed in this paper. The oxidation kinetic was analyzed, the oxidation resistance mechanism of the Al_0.2CrNbTiV coating was clarified with the analysis of the formation and evolution of the oxidation layer, and the effect of the dilution rate on high-temperature performances was revealed. The results showed that the oxide layer was mainly composed of rutile oxides (Ti, Cr, Nb)O₂ after isothermal oxidation at 650 °C and 800 °C for 50 h. The Al_0.2CrNbTiV coating in low dilution exhibited better oxidation performance at 650 °C, due to the dense oxide layer formed with the synergistic growth of fine AlVO₃ particles and (Ti, Cr, Nb)O₂, and higher percentage of Cr, Nb in (Ti, Cr, Nb)O₂ strengthened the lattice distortion effect to inhibit the penetration of oxygen. The oxide layer formed at 800 °C for the Al_0.2CrNbTiV coating was relatively loose, but the oxidation performance of the coating in high dilution improved due to the precipitation of Cr₂Nb-type Laves phases along grain boundaries, which inhibits the diffusion of oxygen. [ABSTRACT FROM AUTHOR]