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Interpolating the radial distribution function in a two-dimensional fluid across a wide temperature range.

Authors :
Kryuchkov, Nikita P.
Nasyrov, Artur D.
Denisenko, Ilya R.
Yurchenko, Stanislav O.
Source :
Journal of Chemical Physics; 9/7/2024, Vol. 161 Issue 9, p1-12, 12p
Publication Year :
2024

Abstract

Calculations of pair correlations in fluids usually require resource-intensive simulations or integral equations, while existing simple approximations lack accuracy. Here, we show that the pair correlation function for monolayer fluid-like systems can be decomposed into correlation peaks defined using Voronoi cells. Being properly normalized, these peaks exhibit a universal form, weak temperature dependence, and resemble those of an ideal gas, except for the first peak. As a result, we propose a simple and accurate approach to interpolate the pair correlation functions, suitable for molecular, colloids, and cellular fluids. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
161
Issue :
9
Database :
Complementary Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
179513517
Full Text :
https://doi.org/10.1063/5.0213689