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Stellated cuboctahedron of FeIII.
- Source :
- Angewandte Chemie; 9/9/2024, Vol. 136 Issue 37, p1-5, 5p
- Publication Year :
- 2024
-
Abstract
- The solvothermal reaction of FeCl2 ⋅ 4H2O and H4TBC[4] in a basic dmf/EtOH solution affords an [FeIII18] Keplerate conforming to a stellated cuboctahedron. Magnetic and heat capacity measurements reveal spin frustration effects arising from the high symmetry. A crossover between inverse and direct magnetocaloric effects is observed at ~10 K for applied‐field changes lower than 3 T. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 136
- Issue :
- 37
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 179393475
- Full Text :
- https://doi.org/10.1002/ange.202405666