Electronic and Molecular Structures of a Series of Nickel Bis‐1,1‐Dithiolates.

A series of homoleptic Ni bis‐1,1‐dithiolates, [Ni(S2C2RR′)2]2− (R=CN, R′=CN, CO2Et, CONH2, Ph, Ph‐4‐Cl, Ph‐4‐OMe, Ph‐4‐NO2, Ph‐3‐CF3, Ph‐4‐CF3, Ph‐4‐CN; R=NO2, R′=H; R=R′=CO2Et) have been synthesized from the reaction of the alkali metal salt of the ligand and nickel chloride, and isolated as tetraphenylphosphonium or tetrabutylammonium salts. The complexes were characterized by X‐ray crystallography, high‐resolution mass spectrometry, and infrared (IR), nuclear magnetic resonance (NMR) and electronic absorption spectroscopies. The molecular structures show a rigidly square planar Ni(II) center linking two four‐membered chelate rings whose dimensions are constant across the series. The electronic effect of the ligand substituent is revealed in the 13C NMR and electronic spectra, and corroborated by density functional calculations. Electron withdrawing groups deshield the low‐field CS2 resonance, and the signature charge transfer band in the visible region is red‐shifted. These observables have been accurately reproduced computationally, and revealed the Ni contribution to the ground state diminishes with decreasing electron withdrawing capacity of the ligand substituent. In contrast to 1,2‐dithiolates, the redox inactivity afforded by 1,1‐dithiolates stems from the smaller chelate ring and substantially reduced sulfur content that is key to stabilizing the radical form. [ABSTRACT FROM AUTHOR]