Feedstock effect on CO2 gasification of the biomass char generated by fast pyrolysis: a comparative assessment of 40 wood varieties.

Char gasification is a feasible technology to recycle CO₂ and utilize biomass energy. However, the impact of different species of biomass on the gasification is still unclear. For the assessment of the feedstock effect on CO₂ gasification, the present work prepared over 40 different wood char samples on a high temperature (around 1523 K) flame reactor, which simulate the rapid heating rates experienced in industrial reactors. Then, the curves of conversion (X) and conversion rate (dX/dt) versus temperature, and the conversion rate versus fractional conversion were derived from the linear non-isothermal thermogravimetric analysis. Three models (volumetric model, grain model, and random pore model) are examined for their goodness of fit between the model and experimental data, and their estimated activation energy. Finally, links between different biomass property parameters and different reactivity indexes were investigated. The results obtained show that different feedstocks result in different gasification reactivities of the resultant chars, with T50 and T_max varying in a wide range of about 170 K and 200 K. But when conversion is plotted against dimensionless temperature, regardless of the feedstock origin, all the experimental plots can be described by only one curve for X = 0.2–0.95. We attributed the slightly superior prediction of the RPM to the increased amount of adjustable kinetic parameters, but lower E values were obtained by using RPM. In addition to the potassium content, the cellulose and lignin contents of the feedstock were found to have relatively high correlation with the char reactivity indexes. [ABSTRACT FROM AUTHOR]