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Effective elimination of Hg(II) from water bodies with acid-modified magnetic biomass spent coffee grounds: conditional optimization and application.
- Source :
- Environmental Science & Pollution Research; Jul2024, Vol. 31 Issue 31, p44289-44307, 19p
- Publication Year :
- 2024
-
Abstract
- To maximize the efficiency of biomass waste utilization and waste management, a novel acid-modified magnetic biomass spent coffee grounds (NiFe<subscript>2</subscript>O<subscript>4</subscript>/SCG) was obtained by pyrolysis at 473 K and co-precipitation methods and employed to eliminate bivalent mercury (Hg(II)) in water bodies. The prepared NiFe<subscript>2</subscript>O<subscript>4</subscript>/SCG adsorbent exhibits remarkable magnetism with a strength of 45.78 emu/g and can easily be separated from water via a magnetic force. The adsorption of Hg(II) over the NiFe<subscript>2</subscript>O<subscript>4</subscript>/SCG has an optimal conditions of pH = 8, T = 39 ℃, and dosage of 0.055 g/L, and the maximal adsorption capacity for Hg(II) is 167.44 mg/g via Response Surface Methodology optimization. The removal of Hg(II) over NiFe<subscript>2</subscript>O<subscript>4</subscript>/SCG primarily involves ion exchange, electrostatic attraction, and chelation; conforms to the pseudo-second-order kinetic and Langmuir models; and is an endothermic reaction. Additionally, the magnetic biomass NiFe<subscript>2</subscript>O<subscript>4</subscript>/SCG has good regeneration capability and stability. The application research reveal that inorganic salt ions, nitrogen fertilizer urea, humus, and other contaminants in different actual water bodies (river water, lake water, and the effluent of sewage treatment plant) have little effect on the adsorption of Hg(II) over the NiFe<subscript>2</subscript>O<subscript>4</subscript>/SCG. The prepared adsorbent NiFe<subscript>2</subscript>O<subscript>4</subscript>/SCG has practical application value for removing Hg(II) from water bodies. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09441344
- Volume :
- 31
- Issue :
- 31
- Database :
- Complementary Index
- Journal :
- Environmental Science & Pollution Research
- Publication Type :
- Academic Journal
- Accession number :
- 178462636
- Full Text :
- https://doi.org/10.1007/s11356-024-34058-3