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Synthesis, structure and spectroscopic properties of CuL(MeOH), H2L = ( E )- N 1 -(2-((2-aminocyclohexydiimino)(phenyl)methyl)-4-chlorophenyl)- N 2 -(2-benzyl-4-chlorophenyl)oxalamide.
- Source :
- Journal of Coordination Chemistry; 7/10/2005, Vol. 58 Issue 10, p857-862, 6p, 1 Diagram, 2 Charts, 1 Graph
- Publication Year :
- 2005
-
Abstract
- A new kind of copper(II) complex, CuL(MeOH) (H2L?=?( E )- N 1 -(2-((2-aminocyclohexydiimino)(phenyl)methyl)-4-chlorophenyl)- N 2 -(2-benzyl-4-chlorophenyl)oxalamide) has been synthesized and its structure determined by single-crystal X-ray methods. Copper(II) ion is five-coordinate, bonding to four nitrogen atoms from H2L and one oxygen atom from MeOH. Hydrogen bonds in the crystal result in the formation of a one-dimensional structure. EPR spectra are discussed. Computer simulation gave g||?=?2.200, g??=?2.002. On the basis of the synthesis and the crystal structure, the mechanism of the metal template reaction involved in the formation of the complex was verified. [ABSTRACT FROM AUTHOR]
- Subjects :
- COPPER compounds
COMPLEX compounds
OXYGEN
NITROGEN
ATOMS
X-rays
Subjects
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 58
- Issue :
- 10
- Database :
- Complementary Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 17784325
- Full Text :
- https://doi.org/10.1080/00958970412331336358