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Electrochemical quinuclidine-mediated Minisci-type acylation of N-heterocycles with aldehydes.
- Source :
- Chemical Communications; 6/18/2024, Vol. 60 Issue 48, p6174-6177, 4p
- Publication Year :
- 2024
-
Abstract
- The electro-generation of acyl radicals from both aromatic and aliphatic aldehydes remains an unmet challenge. We provide a solution to this challenge by merging electro-oxidation and a quinuclidine-mediated hydrogen atom transfer strategy. The generation of acyl radicals at decreased applied potentials compared to that of formyl oxidation exhibits excellent functional group compatibility. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 48
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 177802162
- Full Text :
- https://doi.org/10.1039/d4cc00800f