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Crystal structure and Hirshfeld surface analysis of (Z)-4-({[2-(benzo[b]thiophen-3-yl)cyclopent-1-en-1-yl]methyl}(phenyl)amino)-4-oxobut-2-enoic acid.

Authors :
Yakovleva, Elizaveta D.
Shelukho, Evgeniya R.
Grigoriev, Mikhail S.
Hasanov, Khudayar I.
Sadikhova, Nurlana D.
Akkurt, Mehmet
Bhattarai, Ajaya
Source :
Acta Crystallographica Section E: Crystallographic Communications; Apr2024, Vol. 80 Issue 5, p537-542, 12p
Publication Year :
2024

Abstract

In the title compound, C<subscript>24</subscript>H<subscript>21</subscript>NO<subscript>3</subscript>S, the cyclopentene ring adopts an envelope conformation. In the crystal, molecules are linked by C--H...π interactions, forming ribbons along the a axis. Intermolecular C--H...O hydrogen bonds connect these ribbons to each other, forming layers parallel to the (011) plane. The molecular packing is strengthened by van der Waals interactions between the layers. The intermolecular contacts were quantified using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing the relative contributions of the contacts to the crystal packing to be H...H 46.0%, C...H/H...C 21.1%, O...H/H...O 20.6% and S...H/H...S 9.0%. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
20569890
Volume :
80
Issue :
5
Database :
Complementary Index
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
177305269
Full Text :
https://doi.org/10.1107/S2056989024003232