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Pure separation of acetylene based on a sulfonic acid and amino group functionalized Zn-MOF.
- Source :
- Chemical Communications; 5/11/2024, Vol. 60 Issue 38, p5046-5049, 4p
- Publication Year :
- 2024
-
Abstract
- The dual-ligand strategy was employed to synthesize a new microporous material, [Zn<subscript>3</subscript>(SNDC)(AmTAZ)<subscript>3</subscript>(H<subscript>2</subscript>O)]·H<subscript>2</subscript>O·CH<subscript>3</subscript>CN (1), incorporating sulfonic acid and amino groups for enhancing gas adsorption and separation. The activated 1 (named 1a) exhibited selective adsorption of acetylene over carbon dioxide and methane. Hence, the dual-ligand strategy optimized the pore environment and provided an effective approach for pure separation of gases. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 38
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 177263266
- Full Text :
- https://doi.org/10.1039/d4cc00863d