Waste Biomass-Mediated Synthesis of TiO 2 /P, K-Containing Grapefruit Peel Biochar Composites with Enhanced Photocatalytic Activity.

In this study, TiO₂/P, K-containing grapefruit peel biochar (TiO₂/P, K-PC) composites were synthesized in situ biomimetically using grapefruit peel as the bio-template and carbon source and tetrabutyl titanate as the titanium source. This was achieved using the two-step rotary impregnation–calcination method. Adjusting the calcination temperature of the sample in an air atmosphere could regulate the mass ratio of TiO₂ to carbon. The prepared samples were subjected to an analysis of their compositions, structures, morphologies, and properties. It demonstrated that the prepared samples were complexes of anatase TiO₂ and P, K-containing carbon, with the presence of graphitic carbon. They possessed a unique morphological structure with abundant pores and a large surface area. The grapefruit peel powder played a crucial role in the induction and assembly of TiO₂/P, K-PC composites. The sample PCT-400-550 had the best photocatalytic activity, with the degradation rate of RhB, MO, and MB dye solutions reaching more than 99% within 30 min, with satisfactory cyclic stability. The outstanding photocatalytic activity can be credited to its unique morphology and the efficient collaboration between TiO₂ and P, K-containing biochar. [ABSTRACT FROM AUTHOR]