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Potassium-promoted Ru-MCM-41 catalyst via in situ loading for effective low-temperature ammonia decomposition.
- Source :
- New Journal of Chemistry; 5/14/2024, Vol. 48 Issue 18, p8195-8202, 8p
- Publication Year :
- 2024
-
Abstract
- A potassium (K)-promoted Ru-based siliceous molecular sieve catalyst, K-nRu-MCM-41, was successfully synthesized via a hydrothermal method. The combined analysis of XRD, FT-IR and XPS data revealed that Ru exists in the framework of the molecular sieves as RuO<subscript>2</subscript> species, leading to structural alterations. SEM and TEM images demonstrated that Ru doping disrupts the morphology of the molecular sieves, while K addition effectively preserves the original morphology and further enhances particle dispersion. The ammonia decomposition performance test indicated that K promotes the activity of the molecular sieve catalysts. At 450 °C and 12 000 mL g<subscript>cat</subscript><superscript>−1</superscript> h<superscript>−1</superscript>, K-4Ru-MCM-41 achieved 82.7% ammonia conversion and 253.6 mmol g<subscript>Ru</subscript><superscript>−1</superscript> min<superscript>−1</superscript> hydrogen production, respectively, which was a 7.6% increase in ammonia conversion compared with 4Ru-MCM-41. Furthermore, the K-4Ru-MCM-41 catalyst exhibited excellent reusability, maintaining its stable catalytic activity performance after 30 h. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 48
- Issue :
- 18
- Database :
- Complementary Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 177061828
- Full Text :
- https://doi.org/10.1039/d3nj05953g