Evaluation of structure-reactivity correlation of efficient corrosion inhibitor ionic liquids for mild steel in acidic medium.

The synthesis and characterization of Imidazolium cation-based ionic liquids having different anions were reported in the present article. The physicochemical and spectral analyses were used to characterized these ionic liquids. The theoretical studies using the B₃LYP method provide optimized structure, HOMO–LUMO plots, thermodynamic parameters, and quantum descriptors. The anti-corrosive property of Imidazolium cation-based ionic liquids was observed in 0.5 M H₂SO₄ corrosive medium at 303, 313, 323, and 333 K temperatures by various strategies like gravimetric studies, electrochemical impedance spectroscopy, potentiodynamic polarization studies, and scanning electron microscopy (SEM). The interesting feature of this article is that both ionic liquids follow different adsorption isotherms. IL-1 ionic liquid shows physisorption adsorption behavior, and IL-2 exhibits mixed adsorption (chemisorptions and physiorption). The electrochemical strategies and E_gap value obtained from DFT reveal the maximum inhibition efficiency of IL-2 for the corrosion process in an acidic medium on mild steel. Potentiodynamic polarization studies reveal the mixed type behavior for ionic liquid inhibitors. EIS results indicate that the inhibition efficiency improved by enhancing ionic liquids concentration. The protective layer formation or adsorption of ionic liquid on metallic surface was confirmed by SEM. In the present article, the proposed mechanism shows the blockage of anodic and cathodic sites by ionic liquids to inhibit the corrosion process on mild steel in an acidic medium. [ABSTRACT FROM AUTHOR]