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Cu/TiO2 Photocatalysts for CO2 Reduction: Structure and Evolution of the Cocatalyst Active Form.
- Source :
- Transactions of Tianjin University; Apr2024, Vol. 30 Issue 2, p140-151, 12p
- Publication Year :
- 2024
-
Abstract
- Extensive work on a Cu-modified TiO<subscript>2</subscript> photocatalyst for CO<subscript>2</subscript> reduction under visible light irradiation was conducted. The structure of the copper cocatalyst was established using UV–vis diffuse reflectance spectroscopy, high-resolution transmission electron microscopy, X-ray absorption spectroscopy, and X-ray photoelectron spectroscopy. It was found that copper exists in different states (Cu<superscript>0</superscript>, Cu<superscript>+</superscript>, and Cu<superscript>2+</superscript>), the content of which depends on the TiO<subscript>2</subscript> calcination temperature and copper loading. The optimum composition of the cocatalyst has a photocatalyst based on TiO<subscript>2</subscript> calcined at 700 °C and modified with 5 wt% copper, the activity of which is 22 µmol/(h·g<subscript>cat</subscript>) (409 nm). Analysis of the photocatalysts after the photocatalytic reaction disclosed that the copper metal on the surface of the calcined TiO<subscript>2</subscript> was gradually converted into Cu<subscript>2</subscript>O during the photocatalytic reaction. Meanwhile, the metallic copper on the surface of the noncalcined TiO<subscript>2</subscript> did not undergo any transformation during the reaction. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10064982
- Volume :
- 30
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- Transactions of Tianjin University
- Publication Type :
- Academic Journal
- Accession number :
- 176727241
- Full Text :
- https://doi.org/10.1007/s12209-024-00384-3