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Modular Synthesis of Improbable Rotaxanes with All‐Benzene Scaffolds.
- Source :
- Angewandte Chemie International Edition; Apr2024, Vol. 63 Issue 18, p1-6, 6p
- Publication Year :
- 2024
-
Abstract
- "Improbable" rotaxanes consisting of interlocked conjugated components represent non‐trivial synthetic targets, not to mention those with all‐benzene scaffolds. Herein, a modular synthetic strategy has been established using an isolable azo‐linked pre‐rotaxane as the core module, in which the azo group functions as a tracelessly removable template to direct mechanical bond formations. Through versatile connections of the pre‐rotaxane and other customizable modules, [2]‐ and [3]rotaxanes derived from all‐benzene scaffolds have been accomplished, demonstrating the utility and potential of the synthetic design for all‐benzene interlocked supramolecules. [ABSTRACT FROM AUTHOR]
- Subjects :
- ROTAXANES synthesis
ROTAXANES
SUPRAMOLECULES
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 63
- Issue :
- 18
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 176690581
- Full Text :
- https://doi.org/10.1002/anie.202401838