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Mononuclear Fe(III) complexes with 2,4-dichloro-6-((quinoline-8-ylimino)methyl)phenolate: synthesis, structure, and magnetic behavior.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 4/21/2024, Vol. 53 Issue 15, p6809-6817, 9p
- Publication Year :
- 2024
-
Abstract
- Three Fe(III)-based coordination complexes [Fe(dqmp)<subscript>2</subscript>](NO<subscript>3</subscript>)·H<subscript>2</subscript>O (1), [Fe(dqmp)<subscript>2</subscript>](BF<subscript>4</subscript>)·2CH<subscript>3</subscript>COCH<subscript>3</subscript> (2), and [Fe(dqmp)<subscript>2</subscript>](ClO<subscript>4</subscript>) (3) were synthesized from Fe(NO<subscript>3</subscript>)<subscript>3</subscript>·9H<subscript>2</subscript>O/Fe(ClO<subscript>4</subscript>)<subscript>3</subscript>·xH<subscript>2</subscript>O, NaBF<subscript>4</subscript>, and 2,4-dichloro-6-((quinoline-8-ylimino)methyl)phenol (Hdqmp) in methanol/acetone and characterized. The structures of complexes 1–3 were determined via single-crystal X-ray crystallography at 100 K and room temperature, and their magnetic properties in the solid and solution forms were investigated. All complexes showed meridional structures with two tridentate dqmp<superscript>−</superscript> ligands coordinated with Fe(III) cations. In the solid state, complex 1 showed an abrupt and complete spin crossover at 225 K, whereas complexes 2 and 3 exhibited an incomplete spin crossover at 135 and 150 K, respectively. In a dimethylformamide solution, the complexes showed counterion-dependent spin transitions. In contrast to the solid state, in solution, complex 1 did not exhibit complete spin crossover. However, complexes 2 and 3 showed more complete spin transitions in solutions than in the solid state. The relaxation times, T<subscript>1</subscript> and T<subscript>2</subscript>, for 1 and 2 were determined and both increased with temperature from 220 to 380 K. The T<subscript>1</subscript> of 1 was larger than that of 2 at 380 K, and the T<subscript>1</subscript> values were larger than the T<subscript>2</subscript> values. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 53
- Issue :
- 15
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 176611099
- Full Text :
- https://doi.org/10.1039/d3dt04385a