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Cyanometallic charge engineering in spin crossover metal–organic frameworks.
- Source :
- Chemical Communications; 4/25/2024, Vol. 60 Issue 32, p4318-4321, 4p
- Publication Year :
- 2024
-
Abstract
- In this study, we successfully synthesize cationic/neutral/anionic inverse-Hofmann-type spin crossover (SCO) frameworks with 1,1,2,2-tetrakis(4-(pyridine-4-yl)phenyl)-ethene ligand by means of cyanometallic charge engineering strategy. The cationic and neutral frameworks exhibit single-step thermally induced spin transition behaviors, while the SCO capability of anionic framework can be aroused by partial desolvation. This strategy provides a new idea to construct ionic SCO frameworks and extends the toolkit for SCO materials. [ABSTRACT FROM AUTHOR]
- Subjects :
- SPIN crossover
METAL-organic frameworks
ENGINEERING
DESOLVATION
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 32
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 176610328
- Full Text :
- https://doi.org/10.1039/d4cc00673a